You'll need to pick a sprite to be your main character. You'll also need a sprite to represent the ground. Finally, you'll need to program your character's starting position.
Put your mouse over the blue cat face, and move it up to the paint brush tool. Click on that to open the sprite editor. Use the rectangle tool in here to draw the ground.
Add a yellow "when green flag clicked" to your player's code. This is found in the "Events" section.
Then, right below it, add a "go to x: _ y: _" from the "motion" section. Don't try to change the coordinates! They'll automatically match to wherever your sprite is right now.